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Student's Corner
Written by Greg Stevens   
Thursday, 02 September 2010 07:41

Our recent news article about algae as a source for bioplastic has received a lot of attention.  But there is something very important that it didn't tell you:

 

You can make your own bioplastic from algae.  And we will give you step-by-step instructions on how to do it.

 

It's a fun little science project.  You can do it in your kitchen, with stuff you buy at the grocery store.  And you can see what "algae bioplastic" really looks and feels like...

First, a little background.  You might not have known this, but when people talk about "seaweed" they are actually talking about a form of algae.  That is what we are talking about in the context of bioplastics: red algae, also known as "red seaweed."  The specific chemical that we are interested in is agar, which appears in red seaweed in abundance.  When you hear Cereplast and other companies talk about developing bioplastic made from seaweed, they really mean that they will be using the chemical agar, which is extracted from the seaweed.

Fortunately (or unfortunately?) this project won't have you traipsing out to the ocean to collect seaweed.  Agar is used as a food additive in confectionaries, desserts, beverages, icecream and health foods.  It's also used as a non-food additive in toothpaste, cosmetics, and adhesives.  It's not that difficult to get: if you can't find it at the grocery store, you can Google "buy agar" and you get plenty of results there.

Before we get to the actual recipe for making your very own "algae plastic", you should understand what role agar actually plays.  Like all other plastics, bioplastics are composed of three basic parts:  one or more polymers, one or more plasticizers, plus one or more additives.  Roughly speaking: polymers give plastic its strength, plasticizers give it its bendable and mouldable qualities, and additives give it other properties (color, durability, etc).  Agar is a biopolymer.

From the Green Plastics book:

Agar, either by itself or in blends with other biopolymers, appears to impart favorable properties to plastic sheets. In plastics containing agar and glycerol (a plasticizer), the effectiveness of the glycerol lasts longer, because the agar seems to slow down the increase in brittleness. Agar also seems to improve resistence to microwave radiation, and it improves clarity in sorbitol formulations. Agar is more expensive than starch, which limits its large-scale use.

Are you ready to try this? You basic procedure for making the bioplastic will be the same as described Brandon's Remix video. The main difference will be in the actual ingredients and proportions.  Here are some suggestions you can try.  Each of the following combinations will produce slightly different plastics with different properties.

Agar Only

3.0 g (1 tsp) agar
240 ml (1 cup) of 1% glycerol solution
180 ml (3/4 cup) water

Agar-Starch Blend

1.5 g (1/2 tsp) sorbitol
3.0 g (1 tsp) starch
3.0 g (1 tsp) agar
240 ml (1 cup) of 1% glycerol solution
300 ml (1 1/4 cup) water
0.75 g (1/2 tsp) agar
120 ml (1/2 cup) of 1% glycerol solution

Gelatin-Agar Blend

2.25 g (3/4 cup) sorbitol
2.25 g (3/4 cup) gelatin
2.25 g (3/4 cup) agar
180 ml (3/4 cup) of 1% glycerol solution
240 ml (1 cup) water

Procedure

The procedure is basically the same in every case.  Mix all of the ingredients together in the amounts above, and stir.  Keep mixing until there are no clumps and it is as dispersed as it's gong to get.  Then heat the mixture to 95 C or to when it starts to froth (whichever comes first). Stir the mixture while you are heating it, and once it is at the right temperature (or starts to froth), remove the heat and keep stirring.  Scoop out excess froth with a spoon, and make sure there are no clumps.  Carefully pour the mixture into a drying pan, and make sure to spread it out to let it dry.

How long it takes will depend on the temperature and humidity in the room, and it may take several days (depending on your formulation). You won't be able to remove the plastic from the drying sheet easily until it is completely dry, so be patient!  If your first batch turns out too sticky or slimy, you can try it again with slightly less plasticizer.  Remember, the above recipes are just starting points.... have fun trying different proportions and combinations, and see what kinds of plastic it makes!

Happy experimenting.

(For many more recipes like these, and a lot of good information about the background and science of bioplastics, get the Green Plastics book.)

 

Comments  

 
0 # Jude Lothridge 2011-03-02 11:54
Does this procedure make plastic film or hard plastic? Or both?
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+3 # Greg Stevens 2011-03-02 17:23
This will make films with different properties (e.g. bendability and thickness). But generally they will not produce a hard, solid plastic.

Another person actually recently asked about how to make a hard, inflexible plastic from something other than gelatin, so I plan on writing a post dedicated to making a hard bioplastic from agar (algae). Please check back again soon and I will post it!
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0 # Jude 2011-03-03 12:01
Alrighty, thanks! I plan on testing this procedure out for myself, soon.
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0 # marri 2011-03-14 14:30
hiii there im very much interested to setup algae bioplastic plant .would be glad if you can let me know weather can this plastic be used as a plastic bag for food and carry bags and even in manufacturing bottles
would be great if you can provide me further information or contact me at
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0 # Isabel 2011-03-25 04:32
Hi,

I just learned about bioplastics and that you can make them on your own. At the moment we have a discussion about bowls and cups from plastic in the kindergarden. We want to get rid of them! Now I thought we might be able to make our own ones. But it seems that the recipes are not for waterproof plastic (that one can put in the dishwasher). Is that right? If so, is there a recipe for waterproof bioplastic? It would be great! Thank for answering.
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0 # Greg Stevens 2011-08-28 12:50
Hi Isabel! We just posted a whole article on the question of making water-proof bioplastics at home. It was a tough one, and hope we hope the article helps!

http://green-plastics.net/discussion/54-student/123-qaa-can-i-make-waterproof-bioplastic
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0 # Scott 2011-04-07 01:50
Great, I look forward to your post on creating hard plastics, will be very useful! Cheers!
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0 # rosie 2011-08-10 22:31
hi, i hope you can post procedures on how to make hard plastics which are waterproof
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0 # Greg Stevens 2011-08-28 12:49
We just posted a new article, all on the topic of making waterproof bioplastic! Enjoy!

http://green-plastics.net/discussion/54-student/123-qaa-can-i-make-waterproof-bioplastic
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0 # nisha 2011-08-17 05:15
hi
can u tell me more methods for producing bioplastic by sending to my mail
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0 # Greg Stevens 2011-08-17 06:28
Absolutely, I will tell your right here!

You can get a LOT of varied recipes for different kinds of bioplastics, including explanations for why different bioplastics have different properties and detailed instructions for how to make them, from the book "Green Plastics" by E.S.Stevens.

The amazon link is here:

http://www.amazon.com/Green-Plastics-Introduction-Biodegradable-Plastics/dp/069104967X/
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0 # #Ashish Rathore 2011-08-25 04:52
Thanks 4 d info given above but the plastic produced from above method ll b hydrophobic or hydrophilic?
Can it withstand water? and if not can you pls post how to make above plastic water repellent?
Thank you.
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+1 # Greg Stevens 2011-08-28 12:52
Hi there! We actually had so many requests for this info, we have posted an entire article about water-resistance and bioplastic. Hope this helps!

http://green-plastics.net/discussion/54-student/123-qaa-can-i-make-waterproof-bioplastic
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0 # Ashish Rathore 2011-09-02 22:08
thank you for your information.
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0 # bioplastics 2011-09-02 14:58
fine and useful
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0 # Aishwarya Ks 2011-10-03 12:04
is the water used regular tap water or distilled water??
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0 # Greg Stevens 2011-10-07 18:29
Regular tap water should work just fine!
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0 # Aishwarya Ks 2011-12-13 08:51
The agar starch blend mentioned above has two different quantities of agar and 1% glycerol solution. Which one of them should we follow? Or do we sum the quantities up?
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0 # hanneuse 2012-02-29 09:59
Does anyone has recipities to make banana plastic which seems very strong plastic. :lol:

http://inhabitat.com/banana-plastic-researchers-create-incredibly-strong-plastic-from-fruits/
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0 # Emma 2012-03-28 07:57
Why do you use glycerol solution? On the agar tin it said to use sugar? And what makes it get harder, adding less water or more?
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0 # Greg Stevens 2012-04-11 18:07
Emma,

The biggest influence on the hardness of the end result will be the amount of glycerin you use. Have a much more diluted glycerol solution, and you will get a harder more brittle plastic; have more glycerin but having a higher concentration glycerol solution, and you will get a more flexible plastic.
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